Solid‐State Near‐Infrared Circularly Polarized Luminescence from Chiral Yb <sup>III</sup> ‐Single‐Molecule Magnet
نویسندگان
چکیده
A field-induced chiral YbIII Single-Molecule Magnet (SMM) displayed an unprecedented near-infrared circularly polarized luminescence (NIR-CPL) in the solid-state. The bridging bis(1,10-phenantro[5,6b])tetrathiafulvalene triad (L) allowed efficient sensitization of NIR 2F5/2→2F7/2 emission while NIR-CPL is associated to f-f transitions ion bearing β-diketonate derived-camphorate ancillary ligands.
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2021
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202100903